Chemistry and Materials
type: channel
description: Chemistry and Materials is an international, peer-reviewed, open-access journal published by the Center for Science Innovation, with e-ISSN 2828-2310 and p-ISSN 2828-271X. The journal publishes original research articles, reviews, and short communications in all areas of chemistry, applied chemistry, and materials science demonstrating novelty and clear contributions to the field. As an open-access journal, Chemistry and Materials makes all published content freely accessible to readers worldwide, promoting the rapid exchange of scientific ideas. The journal is indexed in CAS (American Chemical Society), DOAJ, COPERNICUS, Google Scholar, GARUDA, and other platforms, ensuring broad visibility and reach within the global scientific community.
publisher: Pusat Inovasi Sains
language: en
publication name: Chemistry and Materials
issn: 2828-271X
items: The Formation of New Complexes from a Decomposition of [AuI6AgI3CuII3]3+ Parent Framework during Co-crystallization Process
items: Transmetallation Reaction of Alkali and Alkaline-earth Metal Ions in Supramolecular Complex of [{Au6Cd3(tdme)2(D-pen)6}Cd4Na4](NO3)12
items: Covalent Organic Framework (COFs) in Targeted Drug Delivery and Therapeutics: A Critical Review
items: Electrodeposition of CZTS Thin Films with Na₂SO₃ Additive for Improved Photoelectrochemical Water Splitting Efficiency
items: NATURAL RUBBER LATEX–BIOACTIVE GLASS COMPOSITE AS A DRUG DELIVERY SYSTEM FOR AMPICILLIN
items: Phytochemical Profiling of Almond Shells: Comparative Analysis of Different Solvent Extracts
items: Synthesis of AuCu Bimetallic Nanoparticles via Electrodeposition for DPPH Free Radical Scavenging and HaCaT Cell Assays
items: Synthesis and Characterization of NiCo Bimetal Electrocatalyst for Water Splitting
items: Triazoles in the Carbohydrate World: Unlocking Multifunctional Glycohybrids
items: Cobalt Decoration on Cu₂O Photocatalyst via Electrodeposition for Enhanced Methylene Blue Degradation
items: https://journal.piscience.org/cma/article/view/115
items: Tunable Film Density of Electrodeposited Gold Nanoparticles for Enhanced Antioxidant Activity
items: Synthesis of Hematite Using Different Additives and The Fabrication of Hematite/SiO₂ Composite
items: Synthesis of Co-doped Cu2O via Photoelectrodeposition
items: Potentiostatic Electrodeposition of FeCo Thin Films: Influence of Deposition Temperature and Saccharin Concentration
items: Comparative Study of the Catalytic Activities of Ni, NiCo, and PtNiCo in Ethanol Electrooxidation: Contributions of Individual Metals
items: Methylene Blue Adsorption using Magnetite-Modified Tea Waste Adsorbent
items: PtSnNi Trimetallic and Their Catalytic Activities in Ethanol Electrooxidation
items: Synthesis of α-Fe2O3 and α-Fe2O3/SiO2 Composite from Geothermal Waste by Sol-Gel Method and Their Characterization
items: Morphology-Dependent Antioxidant Activity of Gold Nanoparticles Prepared Using Different Electrolyte Concentrations
items: Effect of Mass and Contact Time of Coffee Grounds in Nickel Metal Ion Adsorption on Liquid Waste of Chemistry Laboratory
items: The effect of Phase Composition on the Photocatalytic Activity of Cu₂O/CuO/Cu Composites for Methylene Blue Photodegradation
items: The Effect of Saccharin on SnNi Alloy: the Electrodeposition and its Electrocatalytic Activity in Ethanol Oxidation Reaction
items: Electrodeposition of Thin Film Cu-Zn-Sn Alloy for Water Splitting Application
items: Additive-free Electrodeposition of SnCoNi Trimetallic Catalysts for Ethanol Electrooxidation
items: Synthesis of Copper(I) Oxide Thin Film Through Potentiostatic Electrodeposition as an Antioxidant Film
items: Decorating Cu2O with Copper Metal (Cu) through Facile Electrochemical Deposition for Methylene Blue Degradation
items: Synthesis Dithizone-Immobilized In Polivinyl Chloride Membranes For Copper Detection in Water
items: Square Wave Pulse Deposition of Gold Nanoparticles for Ethanol EOR Performance and Its Electrochemical Properties Investigation
items: Antioxidant Activity of AuPt Nanoparticle with Square-Wave Pulse Deposition Method

The Formation of New Complexes from a Decomposition of [AuI6AgI3CuII3]3+ Parent Framework during Co-crystallization Process
type: item
description: Co-crystallization in supramolecular complexes often encounters significant challenges, particularly when dealing with highly charged ionic species. One major issue is that the parent complex structure may decompose during the process, while the new structure cannot be obtained using the original method. In this study, we reported the formation of new coordination complexes derived from the decomposition of a framework structure composed of [AuI6AgI3CuII3(tdme)2(D-pen)6(H2O)3]3+. Two decomposition products, [AuI6AgI2CuII2(tdme)2(D-pen)6] and [AuI6AgI2CuII2(tdme)2(D-pen)6][AuI6CuII3(tdme)2(D-pen)6], were isolated as a result of the interruption of [RhII4ZnII4O(L-cys)12]6- through anion-exchange reaction at two different temperature conditions (0 and 25oC) in a co-crystallization process.
subject: Articles
  topic: section
subject: Au supramolecular complex
  topic: keywords
subject: single-crystal X-ray diffraction
  topic: keywords
subject: co-crystallization
  topic: keywords
subject: anion exchange
  topic: keywords
creator: Benny Wahyudianto
creator: Tatsuhiro Kojima
creator: Nobuto Yoshinari
creator: Takumi Konno
rights: Copyright (c) 2026 Benny Wahyudianto, Tatsuhiro Kojima, Nobuto Yoshinari, Takumi Konno https://creativecommons.org/licenses/by/4.0
date: 2026-02-24
publication date: 2026-02-24
starting page: 57
ending page: 62
doi: 10.56425/cma.v5i1.131

Transmetallation Reaction of Alkali and Alkaline-earth Metal Ions in Supramolecular Complex of [{Au6Cd3(tdme)2(D-pen)6}Cd4Na4](NO3)12
type: item
description: One of the advantages of coordination complex with a framework structure is that it facilitates conducting metal exchange reaction or transmetallation, which important for several purposes. In this study, we evaluated transmetallation phenomena in a 116 nuclear complex of [{Au6Cd3(tdme)2(D-pen)6}12Cd4Na4](NO3)12 (1CdNa) using monovalent and divalent metal ions from alkali and alkaline-earth groups, respectively. The metal replacements were carried out in high concentration solution through single-crystal-to-single-crystal manner. The observation focused on the structural refinement based on single-crystal X-ray diffraction data. The results indicated that selective metal exchange occurred exclusively in specific locations. The presence of d-orbital and metal coordination preferences became two pivotal factors to proceed transmetallation in 1CdNa.
subject: Articles
  topic: section
subject: metal exchange reaction
  topic: keywords
subject: single-crystal-to-single-crystal
  topic: keywords
subject: X-ray crystallography
  topic: keywords
creator: Benny Wahyudianto
creator: Tatsuhiro Kojima
creator: Nobuto Yoshinari
creator: Takumi Konno
rights: Copyright (c) 2026 Benny Wahyudianto, Tatsuhiro Kojima, Nobuto Yoshinari, Takumi Konno https://creativecommons.org/licenses/by/4.0
date: 2026-04-06
publication date: 2026-04-06
doi: 10.56425/cma.vi.132

Covalent Organic Framework (COFs) in Targeted Drug Delivery and Therapeutics: A Critical Review
type: item
description: Covalent organic frameworks (COFs) are an emerging type of crystalline, porous polymers which are formed through covalent bonds using designed organic building blocks. Their high pore structuring, high surface area, and modular chemistry make them attractive platforms for targeted drug delivery and multimodal therapeutics. This is a critical review of the developments in the field of foundational COF chemistry to the most recent biomedical applications, especially with regard to drug encapsulation mechanisms (physical adsorption, covalent conjugation, and host-guest interactions), stimulus-responsive release strategies (pH, redox, enzyme, light), and targeting of the host (passive EPR accumulation and active ligand directed delivery). It focuses on discussion around nanoscale COF fabrication and functionalization approaches that permit controlled loading, colloidal stability, and receptor-mediated uptake, and multifunctional and theranostic COF systems that combine photodynamic/photothermal therapy, catalytic nanozyme activity, gene delivery, and multimodal imaging. In the literature, COFs have shown excellent drug loading capabilities and preclinical efficacy potentials. However, translation is a bottleneck due to several factors, including reproducibility, hydrolytic stability of linkages, full pharmacokinetics/toxicology, and scalable GMO-compatible synthesis. It reported methodological heterogeneities with loading/release assays and advocates standardized reporting (DLC, EE, release conditions, pre-/and post-structural characterization) and intensive in vivo PK/PD and immunotoxicity investigations. Lastly, strategic priorities were outlined in the field, which include rational linkage selection of biodegradability, orthogonal post-synthetic modification protocols, integration of computational design tools, and specific translational work to fast-track clinical translation of COF-based nanomedicines. Taken together, this review evaluates the potential and practic…
subject: Articles
  topic: section
subject: covalent organic frameworks
  topic: keywords
subject: targeted drug delivery
  topic: keywords
subject: biomedical applications
  topic: keywords
subject: nanoscale COF fabrication.
  topic: keywords
creator: Henrietta Marcel
creator: Daniel Idowu
creator: Adeyinka Ademilua
creator: Loveth Marcel
creator: Mohammed Abdul-Rahman
creator: Favour Fabuyi
rights: Copyright (c) 2026 Henrietta Marcel, Daniel Idowu, Adeyinka Ademilua, Loveth Marcel, Mohammed Abdul-Rahman, Favour Fabuyi https://creativecommons.org/licenses/by/4.0
date: 2026-02-24
publication date: 2026-02-24
starting page: 1
ending page: 28
doi: 10.56425/cma.v5i1.130

Electrodeposition of CZTS Thin Films with Na₂SO₃ Additive for Improved Photoelectrochemical Water Splitting Efficiency
type: item
description: The global transition toward sustainable energy has accelerated research into clean hydrogen production, with photoelectrochemical (PEC) water splitting emerging as a promising pathway. In this study, Cu₂ZnSnS₄ (CZTS) thin films were prepared through one-step electrodeposition using sodium sulfite (Na₂SO₃) as an additive on indium tin oxide (ITO)-coated glass substrates. Structural characterization confirmed the formation of a crystalline kesterite phase, with the enhanced intensity of the (112) peak indicating improved crystallinity upon additive incorporation. Surface morphology and composition analysis revealed compact films with a uniform elemental distribution. PEC measurements showed a significant increase in photocurrent density from 7.4 mA/cm² to 22.3 mA/cm² at 1.47 V vs. RHE with Na₂SO₃ attributed to enhanced light absorption and efficient charge carrier separation. Optical analysis indicated a bandgap widening from 1.50 eV to 1.60 eV, consistent with a reduction in crystallite size. Impedance analysis showed lower charge transfer resistance under illumination. Hydrogen and oxygen evolution reaction (HER and OER) tests demonstrated lower overpotential and Tafel slopes, indicating faster reaction kinetics. Improved stability was confirmed by a positive shift in the corrosion potential (Ecorr) and a lower corrosion current density (icorr).. Overall, the addition of Na₂SO₃ enhanced the structural, optical, catalytic, and stability properties, making CZTS suitable for solar-driven hydrogen evolution.
subject: Articles
  topic: section
subject: electrodeposition
  topic: keywords
subject: CZTS
  topic: keywords
subject: photoelectrochemical
  topic: keywords
subject: additive
  topic: keywords
creator: Dyah Ayu Larasati
creator: Dyra Aulia Zhafirah
creator: Reinardo Ramawijaya Widakusuma
rights: Copyright (c) 2025 Dyah Ayu Larasati, Dyra Aulia Zhafirah, Reinardo Ramawijaya Widakusuma https://creativecommons.org/licenses/by/4.0
date: 2025-12-30
publication date: 2025-12-30
starting page: 47
ending page: 56
doi: 10.56425/cma.v5i1.118

NATURAL RUBBER LATEX–BIOACTIVE GLASS COMPOSITE AS A DRUG DELIVERY SYSTEM FOR AMPICILLIN
type: item
description: This study evaluates Natural Rubber Latex (NRL)–Bioactive Glass (BG) Composites as carrier for ampicillin. Current drug delivery systems face challenges of uncontrolled release, poor biocompatibility, and unstable therapeutic levels. Incorporating bioactive glass into natural rubber latex was explored to improve compatibility, sustained release, and strength. Biomembranes (NRL with drug and NRL - BG with drug respectively) were polymerized at room temperature for 72 hours. The biomembranes were then characterized using Fourier Transmission – Infra red (FT-IR) spectroscopy, Scanning Electron Microscopy (SEM) and X8-Ray Diffraction (XRD). The drug release mechanism through the skin, tensile strength and elongation at break were also evaluated. Results showed that 86.26% of the protein in the NRL was removed after centrifugation and the FTIR spectra analysis reveals no chemical interaction between the NRL, drug and bioglass as their individual characteristics exhibits solid fusion. Drug release reached about 70% with burst release near 52–54 hours. The mechanical analysis showed that the incorporation of the bioglass improved the tensile strength of the biomembrane significantly. The results confirm that natural rubber latex can act as a transdermal carrier for ampicillin, with bioactive glass further improving the delivery efficiency.
subject: Articles
  topic: section
subject: natural ruber latex
  topic: keywords
subject: bioactive glass
  topic: keywords
subject: ampicillin
  topic: keywords
creator: Idemudia Osayanyobo Lawrence
creator: Falope Funmilola Yetunde
creator: Ahuose Victory Oseosemen
creator: Aboyewa Jumoke Adebisi
creator: Ozoemena Happiness Onyinye
rights: Copyright (c) 2026 Idemudia Osayanyobo Lawrence , Falope Funmilola Yetunde, Ahuose Victory Oseosemen, Aboyewa Jumoke Adebisi, Ozoemena Happiness Onyinye https://creativecommons.org/licenses/by/4.0
date: 2026-03-16
publication date: 2026-03-16
doi: 10.56425/cma.v5i2.128

Phytochemical Profiling of Almond Shells: Comparative Analysis of Different Solvent Extracts
type: item
description: This study investigates the phytochemical profiles, UV-Vis spectrophotometry, IR spectroscopy, and HPLC analyses of local almond shells extracts using different solvents, including deionized water (DW), ethanol, and a mixture of DW:ethanol (1:1). All extracts contained flavonoids, alkaloids, glycosides, carbohydrates, coumarins, phlobatannins, phytosterols, phenols, quinones, resins, saponins, terpenoids, and triterpenoids, with different concentrations. The DW:ethanol mixture extract also showed the presence of anthraquinones, proteins, and amino acids, which were absent in the other extracts. The DW extract exhibited the highest total flavonoid content (117 mg QE/g), whereas the total polyphenol concentration was greatest in the mixture extract (711 mg TAC/g). The FTIR spectra revealed distinct functional peaks for aromatic rings, unsaturated hydrocarbons, esters, carboxylic acids, ketones, phenols, and alcohols in all extracts. HPLC analysis identified seven prominent phenolic compounds in all extracts, namely benzoic acid, cinnamic acid, gallic acid, ferulic acid, quercetin, kaempferol, and naringenin, with varying concentrations. This study highlights the potential of almond shells as a significant source of bioactive compounds that can function as capping and reducing agents in the environmentally friendly synthesis of nanomaterials. The potential of compounds like flavonoids suggests that almond shell extract is a promising candidate for developing antioxidant drugs.
subject: Articles
  topic: section
subject: almond shells extract
  topic: keywords
subject: phytochemicals
  topic: keywords
subject: total phenol flavonoid contents
  topic: keywords
subject: spectroscopy
  topic: keywords
subject: HPLC
  topic: keywords
creator: Bjeen Hakim Hasan
creator: Nidhal Meena Sher Mohammed
rights: Copyright (c) 2025 Bjeen Hakim Hasan, Nidhal Meena Sher Mohammed https://creativecommons.org/licenses/by/4.0
date: 2025-12-05
publication date: 2025-12-05
starting page: 29
ending page: 38
doi: 10.56425/cma.v5i1.127

Synthesis of AuCu Bimetallic Nanoparticles via Electrodeposition for DPPH Free Radical Scavenging and HaCaT Cell Assays
type: item
description: Bimetallic nanoparticles (NPs) have attracted significant interest in biomedical applications due to their unique physicochemical properties and synergistic effects. This study reports the synthesis of bimetallic gold-copper nanoparticles (AuCu NPs) via electrochemical deposition using cyclic voltammetry (CV) on indium tin oxide (ITO) substrates. Various precursor ratios of HAuCl₄ and CuSO₄ were employed to investigate the influence of Cu concentration on morphology and antioxidant activity of AuCu NPs. Characterization using field emission electron microscope equipped with energy dispersive X-ray spectrometer revealed that increasing Cu content altered the particle size distribution and surface uniformity, with optimal homogeneity achieved at a 1:1 Au:Cu ratio, yielding NPs of ~25–27 nm. X-ray diffraction analysis confirmed the presence of crystalline Au and Cu₂O phases, indicating successful co-deposition and surface oxidation of Cu. The antioxidant activity test, assessed through a DPPH radical scavenging assay, showed the highest inhibition (89.09%) for pure Au after a 48-hour incubation, whereas AuCu samples exhibited delayed yet substantial activity (>80%), suggesting time-dependent synergism. Furthermore, MTT assays on HaCaT cells revealed that the AuCu NPs were non-cytotoxic and exhibited protective effects against oxidative stress induced by blue light exposure, highlighting their potential for biomedical and dermatological applications.
subject: Articles
  topic: section
subject: bimetallic AuCu
  topic: keywords
subject: electrodeposition
  topic: keywords
subject: antioxidant activity
  topic: keywords
subject: DPPH assays
  topic: keywords
creator: Norma Nurul Ilmi
creator: Putri Dwi Candra
creator: Sabrina Putri Chaerani
creator: Shirly Harissyah Alfiani
rights: Copyright (c) 2025 Norma Nurul Ilmi, Putri Dwi Candra https://creativecommons.org/licenses/by/4.0
date: 2025-10-31
publication date: 2025-10-31
starting page: 130
ending page: 141
doi: 10.56425/cma.v4i3.113

Synthesis and Characterization of NiCo Bimetal Electrocatalyst for Water Splitting
type: item
description: This research focuses on developing bimetallic nickel‑cobalt (NiCo) electrocatalysts for water‑splitting applications via a tailored electrodeposition approach using saccharin as a structure‑directing additive. The introduction of saccharin refined the material’s crystal size, promoted nickel enrichment in the alloy, and produced a smoother, more porous surface morphology, which collectively enhance the electrochemical active area. The modified catalyst exhibited improved catalytic activity for both hydrogen and oxygen evolution, displaying favorable onset potentials (-0.1593 V for HER and 1.6427 V for OER) and accelerated reaction kinetics, as reflected by Tafel slopes of 134.2 mV/dec and 24.96 mV/dec, respectively. While charge‑transfer resistance was not lowered, long‑term stability and corrosion resistance were markedly enhanced in the presence of saccharin. These results demonstrate that microstructural engineering through additive‑assisted electrodeposition can effectively boost the durability of NiCo electrocatalysts, underscoring the importance of morphology control for sustained performance in energy‑conversion systems.
subject: Articles
  topic: section
subject: catalyst
  topic: keywords
subject: NiCo
  topic: keywords
subject: additive
  topic: keywords
subject: saccharin
  topic: keywords
subject: water splitting
  topic: keywords
creator: Amarisa Nur Affifah
creator: Aulia Setiawan
creator: Qori’atun Ni’mah Salsabila
rights: Copyright (c) 2025 Amarisa Nur Affifah, Aulia Setiawan, Qori’atun Ni’mah Salsabila https://creativecommons.org/licenses/by/4.0
date: 2025-12-29
publication date: 2025-12-29
starting page: 39
ending page: 46
doi: 10.56425/cma.v5i1.119

Triazoles in the Carbohydrate World: Unlocking Multifunctional Glycohybrids
type: item
description: Triazoles have emerged as versatile linkers in carbohydrate chemistry, enabling the construction of stable and multifunctional glycohybrids. This review explores the use of triazoles in carbohydrate chemistry, focusing on how they can be used to create versatile compounds with applications in both medicine and materials science. A variety of glyco-triazole hybrids have been synthesized using efficient and sustainable click chemistry methods. These methods allow for the high-yield joining of sugars to other molecules under biocompatible conditions. This review highlights the diverse biological activities of these new compounds, including their use as antimicrobial, antifungal, and anticancer agents. A cationic chitosan derivative with triazole and quaternary ammonium groups showed strong antifungal and antioxidant properties. Other examples include carbohydrate-derived triazoles that inhibit glycogen phosphorylase, a feasible treatment for type 2 diabetes, and piperazine triazolyl sugar conjugates that show potent anticancer activity against HeLa cells. Beyond their medicinal uses, the review also covers the application of glyco-triazole hybrids in materials science and sensing. This review emphasises that while significant progress has been made, future work should focus on designing more complex structures, using greener synthesis methods, and addressing challenges like bioavailability and stability to move these promising compounds from the laboratory to real-world applications.
subject: Articles
  topic: section
subject: carbohydrates
  topic: keywords
subject: click chemistry
  topic: keywords
subject: triazoles
  topic: keywords
creator: Jyoti Dahiya
creator: Anudeep Kumar Narula
creator: Gulshan Kumar
rights: Copyright (c) 2025 Jyoti Dahiya, Anudeep Kumar Narula; Gulshan Kumar https://creativecommons.org/licenses/by/4.0
date: 2025-10-31
publication date: 2025-10-31
starting page: 79
ending page: 98
doi: 10.56425/cma.v4i3.123

Cobalt Decoration on Cu₂O Photocatalyst via Electrodeposition for Enhanced Methylene Blue Degradation
type: item
description: Cuprous oxide (Cu₂O) is a promising material for photocatalysis due to its narrow bandgap, cost-effectiveness, and non-toxicity. However, its practical application is hindered by the rapid recombination of electron-hole pairs and low stability. This study addresses these limitations by decorating Cu₂O film with a cobalt (Co) cocatalyst. The Cu₂O/Co film was successfully synthesized on indium tin oxide (ITO) substrate through electrodeposition. Characterisation results confirmed the presence of small, agglomerated Co deposits that scattered on Cu2O grain boundaries. Electrochemical impedance spectroscopy showed that Cu₂O/Co exhibited a charge transfer resistance of 21.94 Ω, which is lower compared to Cu₂O at 24.16 Ω. This indicates that the addition of Co enhances interfacial charge transfer kinetics. Photodegradation test of Cu₂O with Co then revealed a higher degradation efficiency of 76.51% than that of Cu₂O film at 67.55%, highlighting the potential of Co as a cocatalyst for Cu2O.
subject: Articles
  topic: section
subject: cobalt cocatalyst
  topic: keywords
subject: Cu2O
  topic: keywords
subject: electrodeposition
  topic: keywords
subject: methylene blue
  topic: keywords
subject: photodegradation
  topic: keywords
creator: Bella Pricilya
creator: Nindys Aprillia
creator: Shyla Noureen Zahra
creator: Firgie Wulandari
creator: Faisal Abnisa
rights: Copyright (c) 2025 Bella Pricilya, Nindys Aprillia, Shyla Noureen Zahra, Firgie Wulandari, Faisal Abnisa https://creativecommons.org/licenses/by/4.0
date: 2025-10-31
publication date: 2025-10-31
starting page: 99
ending page: 106
doi: 10.56425/cma.v4i3.122

https://journal.piscience.org/cma/article/view/115
type: item
title: Green design, synthesis, and characterization of a novel eight-membered silicon-boron-based cyclo-1,5-di(p-tolyl)-3,3,7,7-tetraphenyl-1,5-dibora-3,7-disiloxane, a Lewis acid, and its use for the adsorption of Fe3+ and Methylene blue from aqueous solution
description: Metal ions such as Fe3+ and dye contamination such as methylene blue (MB) have caused environmental and health problems, particularly through industrial wastewater discharge. Some conventional treatment methods of removing these toxins are inefficient and unsustainable. Thus, this study focuses on the synthesis and characterization of cyclo-1,5-di(p-tolyl)-3,3,7,7-tetraphenyl-1,5-dibora-3,7-disiloxane, a Lewis acid, and its application in the adsorption of Fe3+ and MB from aqueous solution. The compound was synthesized via a condensation reaction between diphenylsilanediol (4.3 g, 19.97 mmol) and p-tolylboronic acid (2.72 g, 20.03 mmol) at reflux for 12 h. The crude product was recrystallized from petroleum ether yielding 2.89 g of blocky, colorless crystals (90% yield, melting point 260 °C). The compound was characterized using powder X-ray diffraction (PXRD) and fourier transform infrared (FT-IR) spectroscopy. Thereafter, the synthesized compound was used for the adsorption of Fe3+ and MB. The adsorption isotherms for both Fe3+ and MB follow the Freundlich with R2 values of 0.8967 and 0.8769, respectively. These adsorption study results show the potential of the synthesized novel compound, as an adsorbent for the removal of Fe3+ and MB in aqueous solution, offering a promising future for application in wastewater treatment and environmental remediation.
subject: Articles
  topic: section
subject: diphenylsilanediol
  topic: keywords
subject: p-tolylphenylboronic acid
  topic: keywords
subject: cyclodiborasiloxane
  topic: keywords
subject: iron(III)
  topic: keywords
subject: methylene blue
  topic: keywords
creator: Okpara Sergeant Bull
creator: Tubonimi Joseph Kio Ideriah
creator: Godstime Tamunofri Adirimo
rights: Copyright (c) 2025 Okpara Sergeant Bull, Tubonimi Joseph Kio Ideriah, Godstime Tamunofri Adirimo https://creativecommons.org/licenses/by/4.0
date: 2025-10-31
publication date: 2025-10-31
starting page: 107
ending page: 116
doi: 10.56425/cma.v4i3.115

Tunable Film Density of Electrodeposited Gold Nanoparticles for Enhanced Antioxidant Activity
type: item
description: The synthesis of gold nanoparticles (AuNPs) is a critical aspect in the development of large-scale antioxidant nanomaterials. Although, biological methods offer a non-toxic reagent and an environmentally friendly route for synthesis. However, their scalability is limited by the non-uniformity of particle size, the scarcity of biological materials, the challenges associated with controlling organism growth, and the relatively long synthesis time. Therefore, chemical methods, especially electrodepositions, are preferred due to their effectiveness, efficiency, and the ability to precisely control particle size and shape through electrolyte modifications. In this study, two supporting electrolytes, KCl and Na₂SO₄, were employed. The results demonstrated that the type of electrolyte ion significantly influences the particle density of the AuNPs, with KCl electrolyte providing a higher particle density. This increased particle density correlates with a larger active surface area per unit area, subsequently enhancing the antioxidant activity of the AuNPs, as evidenced by up to 57% DPPH inhibition. Furthermore, cytotoxicity and cytoprotective assays indicated good biocompatibility and protective capabilities of AuNPs.
subject: Articles
  topic: section
subject: AuNPs
  topic: keywords
subject: supporting electrolyte
  topic: keywords
subject: particle density
  topic: keywords
subject: antioxidant activity
  topic: keywords
creator: Babay Asih Suliasih
creator: Charzen Mae Kinoan
rights: Copyright (c) 2025 Babay Asih Suliasih, Charzen Mae Kinoan https://creativecommons.org/licenses/by/4.0
date: 2025-06-30
publication date: 2025-06-30
starting page: 72
ending page: 78
doi: 10.56425/4q3vyc49

Synthesis of Hematite Using Different Additives and The Fabrication of Hematite/SiO₂ Composite
type: item
description: Hematite (α-Fe₂O₃) is a widely studied iron oxide due to its broad functional versatility in catalysis, sensing, and environmental applications. However, controlling its morphology and crystallinity remains a challenge, which limits its performance in composite materials. This study investigates the role of sodium hydroxide and citric acid as additives to identify optimal hematite characteristics on the fabrication of hematite/SiO₂ composite via the sol-gel method. Sodium hydroxide serves as a source of hydroxide ions, accelerating nucleation and acting as a precipitating agent, while citric acid chelates Fe³⁺ ions and caps growing nuclei, which enhances crystallinity and suppresses particle agglomeration. As a result, hematiteCA exhibited brownish-purple appearance and higher crystallinity, whereas hematiteSH showed larger and more agglomerated particles. Integrating silica into hematiteCA produced wine-red hematite/SiO2 composites and porous-like surface morphology. These findings demonstrate that additive selection is a critical parameter in synthesizing hematite microstructure and enhancing its compatibility with silica, thereby enabling the development of composites for advanced applications.
subject: Articles
  topic: section
subject: hematite
  topic: keywords
subject: additives
  topic: keywords
subject: silica
  topic: keywords
creator: Shirly Harissyah Alfiani
creator: Qori'atun Ni'mah Salsabila
creator: Reinardo Ramawijaya Widakusuma
creator: Agus Purwanto, Ph.D
creator: Rifqi Almusawi Rafsanjani
creator: Habib Muhammad Zapar
creator: Bagaskoro Pranata Ardhi
rights: Copyright (c) 2025 Shirly Harissyah Alfiani, Qori'atun Ni'mah Salsabila, Reinardo Ramawijaya Widakusuma, Agus Purwanto, Ph.D, Rifqi Almusawi Rafsanjani, Habib Muhammad Zapar, Bagaskoro Pranata Ardhi https://creativecommons.org/licenses/by/4.0
date: 2025-10-31
publication date: 2025-10-31
starting page: 117
ending page: 129
doi: 10.56425/cma.v4i3.107

Synthesis of Co-doped Cu2O via Photoelectrodeposition
type: item
description: The superior optical and electronic properties of Cu₂O make it a promising semiconductor material for various applications. To enhance its performance, several approaches have been explored, including cobalt (Co) doping, which has been reported to improve light absorption, reduce crystal size, and enhance the crystallinity of Cu₂O. Moreover, the morphology of the material plays a crucial role in determining its functional performance. Photoelectrodeposition offers a unique advantage in tailoring material morphology through light-assisted deposition processes. Therefore, this study aims to investigate the effect of Co concentration on the crystallinity, structure, and morphology of Cu₂O synthesized via photoelectrodeposition. The results demonstrate the successful synthesis of pure Cu₂O and Co-doped Cu₂O phases. X-ray diffraction analysis indicates that Co atoms successfully substitute Cu atoms, leading to a reduction in crystal size. Raman spectroscopy further confirms an increase in oxygen vacancies in the doped samples. In addition, the particle morphology undergoes significant changes attributed to the influence of illumination during the deposition process.
subject: Articles
  topic: section
subject: Cu2O doped Co
  topic: keywords
subject: crystallinity
  topic: keywords
subject: photoelctrodeposition
  topic: keywords
creator: Muhammad Raihan Rauf
creator: Jumaeda Jatmika
creator: Mohammad Hamzah Fauzi
creator: Suci Winarsih
rights: Copyright (c) 2025 Muhammad Raihan Rauf, Jumaeda Jatmika, Mohammad Hamzah Fauzi, Suci Winarsih https://creativecommons.org/licenses/by/4.0
date: 2025-06-30
publication date: 2025-06-30
starting page: 66
ending page: 71
doi: 10.56425/t1s07623

Potentiostatic Electrodeposition of FeCo Thin Films: Influence of Deposition Temperature and Saccharin Concentration
type: item
description: The FeCo thin films were synthesized using a potentiostatic electrodeposition technique under varying deposition temperatures and saccharin compositions. The effects of these parameters on the film’s crystallinity, composition, microstructure, and deposition behavior were systematically investigated. X-ray diffraction confirmed the formation of a single-phase FeCo structure under all conditions. Increasing the deposition temperature enhanced mass transfer and reduced anomalous codeposition behavior, as evidenced by the compositional shift toward higher cobalt content. The presence of saccharin was found to significantly influence the nucleation and growth processes through adsorption and the formation of metal–saccharinate complexes, which altered the deposition behavior. These results demonstrate that optimizing deposition parameters enables precise control over the composition and structure of FeCo thin films, which is crucial for the functional applications of magnetic and electrocatalysis.
subject: Articles
  topic: section
subject: potentiostatic technique
  topic: keywords
subject: electrodeposition
  topic: keywords
subject: saccharin
  topic: keywords
subject: thin film
  topic: keywords
subject: FeCo
  topic: keywords
creator: Ayuningsih Arum
rights: Copyright (c) 2025 Ayuningsih Arum https://creativecommons.org/licenses/by/4.0
date: 2025-06-30
publication date: 2025-06-30
starting page: 50
ending page: 57
doi: 10.56425/rw1dv623

Comparative Study of the Catalytic Activities of Ni, NiCo, and PtNiCo in Ethanol Electrooxidation: Contributions of Individual Metals
type: item
description: This study compares the catalytic activity of Ni, NiCo, and PtNiCo in the ethanol electrooxidation reaction to elucidate the role of each metal. The catalysts were synthesized via electrodeposition at room temperature and characterized using energy-dispersive X-ray spectroscopy and X-ray diffractometry techniques. Catalytic activity was evaluated through various electrochemical tests, including electrochemical impedance spectroscopy, linear sweep voltammetry, and chronoamperometry. Ethanol electrooxidation tests conducted via cyclic voltammetry over 1000 cycles revealed a progressive increase in catalytic activity among the three catalysts, with PtNiCo exhibiting the highest performance. The synergistic effect of the three metals resulted in a low charge transfer resistance (3.46 Ω), a small Tafel slope (156 mV/decade), a high peak current density (32.06 mA/cm²), a low If/Ib ratio, and an enhanced reactant diffusion coefficient. These findings provide valuable insights for designing efficient and high-performance tri-metallic catalysts.
subject: Articles
  topic: section
subject: PtNiCo
  topic: keywords
subject: ethanol electrooxidation
  topic: keywords
subject: electrocatalyst
  topic: keywords
creator: Devi Indrawati Syafei
creator: Yasir Arafat Hutapea
creator: Liana Christiani
rights: Copyright (c) 2025 Devi Indrawati Syafei, Yasir Arafat Hutapea, Liana Christiani https://creativecommons.org/licenses/by/4.0
date: 2025-06-30
publication date: 2025-06-30
starting page: 43
ending page: 49
doi: 10.56425/mdyg7474

Methylene Blue Adsorption using Magnetite-Modified Tea Waste Adsorbent
type: item
description: Methylene blue (MB) is a hazardous waste for living things and the environment. In this study, MB adsorption was carried out using tea waste as an adsorbent. To enhance the adsorption process, activation with HCl and modification with magnetite (Fe3O4) were carried out. The purpose of this study was to determine the effectiveness of using tea waste adsorbent activated and modified with Fe3O4 on methylene blue waste. Tea waste was activated with HCl and modified with Fe3O4 using the coprecipitation method. Two variations of testing were conducted, namely, the variation of pH and contact time. The adsorbent was characterized using Fourier transform infrared and scanning electron microscopy. The results showed that the optimum pH at pH 10 with an adsorption power of 98.4% and a contact time of 90 minutes with an adsorption power of 98.6%, when the adsorbent was applied directly to the methylene blue waste produced an adsorption power of 99%, and an adsorption isotherm model that was suitable using Freundlich isotherm with an R2 value of 0.9704.
subject: Articles
  topic: section
subject: adsorbents
  topic: keywords
subject: methylene blue
  topic: keywords
subject: magnetite
  topic: keywords
subject: tea waste
  topic: keywords
creator: Yussi Pratiwi
creator: Miftah Aulia
creator: Baiq Amelia Riyandari
creator: Devi Nur Anisa
rights: Copyright (c) 2025 Yussi Pratiwi, Miftah Aulia, Baiq Amelia Riyandari, Devi Nur Anisa https://creativecommons.org/licenses/by/4.0
date: 2025-06-30
publication date: 2025-06-30
starting page: 58
ending page: 56
doi: 10.56425/jr1w4h95

PtSnNi Trimetallic and Their Catalytic Activities in Ethanol Electrooxidation
type: item
description: The declining availability of fossil fuels and their environmental impacts have driven the search for cleaner, renewable energy alternatives, such as direct ethanol fuel cells (DEFCs). However, the widespread application of DEFCs faces challenges due to the complex kinetics of ethanol electrooxidation, necessitating the development of effective catalysts. Platinum (Pt) is widely regarded as the most effective catalyst for this process. However, its use is hindered by high costs and susceptibility to poisoning by intermediates formed during the ethanol electrooxidation reaction. To address these issues, the addition of Sn and Ni to the Pt catalyst is expected to enhance its performance. In this study, PtSnNi trimetallics were synthesized using the electrodeposition method. The samples were then characterized using scanning electron microscopy-energy dispersive spectroscopy (SEM-EDX) and electrochemical tests to evaluate their catalytic activity and stability. The SEM image reveals that PtSnNi2 has the smallest particle size compared to other PtSnNi samples. Additionally, the results indicate that PtSnNi2, with a composition of 73% Pt, 26% Sn, and 1% Ni, exhibits the optimal electrolyte concentration, leading to the highest catalytic activity and stability. This is evidenced by the lowest Rct, lowest Ib/If ratio, and highest current density in the ethanol oxidation reaction.
subject: Articles
  topic: section
subject: PtSnNi trimetallic
  topic: keywords
subject: ethanol electrooxidation
  topic: keywords
subject: chemical composition
  topic: keywords
creator: Hilman Syafei
creator: Raudhatul Hadawiyah
creator: Mulya Muhammad Nur
rights: Copyright (c) 2025 Hilman Syafei, Raudhatul Hadawiyah, Mulya Muhammad Nur https://creativecommons.org/licenses/by/4.0
date: 2025-02-28
publication date: 2025-02-28
starting page: 34
ending page: 42
doi: 10.56425/cma.v4i1.90

Synthesis of α-Fe2O3 and α-Fe2O3/SiO2 Composite from Geothermal Waste by Sol-Gel Method and Their Characterization
type: item
description: Iron oxide materials, especially hematite (α-Fe2O3), have many important applications. Improving the characteristics and physical properties of hematite has been widely developed, one of which is to combine it as a composite structure with porous materials such as silica (SiO2) as α-Fe2O3/SiO2 composite. This research aims to synthesize α-Fe2O3 particles and α-Fe2O3/SiO2 composites. The α-Fe2O3/SiO2 composite was successfully synthesized by using geothermal waste as an alternative source of silica prepared by the sol-gel method. Both synthesized samples were characterized by X-ray diffraction, scanning electron microscopy equipped with energy dispersive spectroscopy, and X-ray fluorescence techniques. The results showed that silica composites on hematite structure slightly affect the morphology, color, or particle size compared to α-Fe2O3.
subject: Articles
  topic: section
subject: hematite
  topic: keywords
subject: silica
  topic: keywords
subject: sol-gel
  topic: keywords
subject: geothermal waste
  topic: keywords
creator: Rinda Mulmeyda
creator: Reinardo Ramawijaya Widakusuma
creator: Sabrina Putri Chaerani
creator: Agus Purwanto
creator: Rifqi Almusawi Rafsanjani
creator: Habib Muhammad Zapar
creator: Bagaskoro Pranata Ardhi
rights: Copyright (c) 2025 Rinda Mulmeyda, Reinardo Ramawijaya Widakusuma, Sabrina Putri Chaerani, Agus Purwanto, Rifqi Almusawi Rafsanjani, Habib Muhammad Zapar, Bagaskoro Pranata Ardhi https://creativecommons.org/licenses/by/4.0
date: 2025-02-28
publication date: 2025-02-28
starting page: 24
ending page: 33
doi: 10.56425/cma.v4i1.91

Morphology-Dependent Antioxidant Activity of Gold Nanoparticles Prepared Using Different Electrolyte Concentrations
type: item
description: Antioxidants play a crucial role in protecting the body from oxidative stress by neutralizing free radicals. The synthesis of antioxidant-active materials, such as gold nanoparticles (AuNPs), offers significant advantages due to their unique physicochemical properties. In this study, AuNPs were successfully synthesized using the electrodeposition method on indium-tin oxide substrates, with varying Na₂SO₄ electrolyte concentrations. Scanning electron microscopy analysis confirmed that the synthesized AuNPs exhibited a round to slightly irregular morphology, with an average particle size ranging from 48 to 65 nm. X-ray diffractometer characterization revealed that the nanoparticles possessed a face-centered cubic crystal structure, confirming their high purity. Antioxidant activity was evaluated using the DPPH assay, where AuNPs synthesized with 0.5 M Na₂SO₄ exhibited the highest DPPH inhibition of 72.39%. This enhanced antioxidant performance is attributed to the smaller particle size, which increases the available surface area for free radical neutralization. These findings highlight the potential of electrodeposited AuNPs as effective antioxidants and provide valuable insights into optimizing nanoparticle synthesis for biomedical and nanotechnological applications.
subject: Articles
  topic: section
subject: gold nanoparticles
  topic: keywords
subject: antioxidant activity
  topic: keywords
subject: morphology
  topic: keywords
subject: DPPH assays
  topic: keywords
creator: Azri Farhanah Abd Aziz
creator: Babay Asih Suliasih
rights: Copyright (c) 2025 Azri Farhanah Abd Aziz, Babay Asih Suliasih https://creativecommons.org/licenses/by/4.0
date: 2025-02-28
publication date: 2025-02-28
starting page: 9
ending page: 15
doi: 10.56425/cma.v4i1.93

Effect of Mass and Contact Time of Coffee Grounds in Nickel Metal Ion Adsorption on Liquid Waste of Chemistry Laboratory
type: item
description: Based on Indonesian Government Regulation PP No. 22 of 2021 concerning the implementation of environmental protection and management, the quality standard for nickel in waters is 0.05 mg/L. Nickel waste is very harmful to aquatic and terrestrial ecosystems and poses risks to human health. In this study, nickel waste was treated with coffee grounds using the adsorption method. The purpose of this study was to determine the effect of variations in the mass of coffee grounds and contact time on the adsorption of nickel metal in the liquid waste generated by the UNJ Chemistry laboratory. Coffee grounds are activated with NaOH 0.01 M to increase their adsorption ability. Two tests were conducted, namely, the variation of adsorbent mass and the variation of contact time. Based on the results of testing the variation of adsorbent mass and contact time, the highest percentage of removal was obtained at 91.70% at a mass of 0.05 g with a contact time of 15 minutes. The lowest percentage of removal was 39.56% in a mass of 1.5 g with a contact time of 90 minutes. This research provides a novel approach to heavy metal waste treatment especially nickel metal ion, which can be adapted to enhance waste treatment technologies in the future.
subject: Articles
  topic: section
subject: coffee grounds
  topic: keywords
subject: adsorption
  topic: keywords
subject: nickel
  topic: keywords
subject: liquid waste
  topic: keywords
creator: Inez Trinanda
creator: Yussi Pratiwi
creator: Tritiyatma Hadinugrahaningsih
rights: Copyright (c) 2025 Inez Trinanda, Yussi Pratiwi, Tritiyatma Hadinugrahaningsih https://creativecommons.org/licenses/by/4.0
date: 2025-02-28
publication date: 2025-02-28
starting page: 16
ending page: 23
doi: 10.56425/cma.v4i1.86

The effect of Phase Composition on the Photocatalytic Activity of Cu₂O/CuO/Cu Composites for Methylene Blue Photodegradation
type: item
description: This study investigates the influence of phase composition on Cu₂O/CuO/Cu composites for the degradation methylene blue (MB) under visible light irradiation. Two types of composites, Cu₂O-rich and Cu₂O-poor, were successfully synthesized through electrodeposition method. The results showed that the Cu₂O-rich composite exhibited photocatalytic activity, as indicated by a maximum photocurrent of 13 mA/cm² and the highest optimized MB photodegradation efficiency. This enhanced performance is due to the high Cu₂O phase content, which generates a higher photocurrent density, thereby accelerating the redox reaction in the MB degradation.
subject: Articles
  topic: section
subject: Cu2O/CuO/Cu composite
  topic: keywords
subject: phase composition
  topic: keywords
subject: photodegradation
  topic: keywords
creator: Mokhamad Ali Rizqi Maulana
creator: Aisyaturridha
creator: Bimo TriGoutomo
creator: Amir Mahmud
rights: Copyright (c) 2025 Mokhamad Ali Rizqi Maulana, Aisyaturridha, Bimo TriGoutomo, Amir Mahmud https://creativecommons.org/licenses/by/4.0
date: 2025-02-28
publication date: 2025-02-28
starting page: 1
ending page: 8
doi: 10.56425/cma.v4i1.87

The Effect of Saccharin on SnNi Alloy: the Electrodeposition and its Electrocatalytic Activity in Ethanol Oxidation Reaction
type: item
description: The development of Direct Ethanol Fuel Cell (DEFC) has attracted much attention, as alternative energy sources due to its various advantages. However, among its various advantages, DEFC has several problems, such as the kinetics of the ethanol oxidation reaction. Transition metal-based catalysts such as nickel and tin are considered as potential catalysts for DEFC due to their oxophilic properties that can improve catalytic activity. In this study, the effect of saccharin on SnNi bimetallic alloy catalyst synthesized by electrodeposition method on copper wire substrate was investigated. SnNi samples were characterized by several techniques, including X-ray diffraction, Scanning electron microscopy, and energi dispersive X-ray spectrocopy. Saccharin addition had a significant effect on the morphology, crystallite size, and composition of the catalyst. The presence of saccharin causes the formation of more uniform particles and has a smaller size. The sample with the addition of saccharin had a smaller charge transfer resistance value 4.82 Ω, lower tafel slope by 115 mV/dec, and show higher jf/jb ratio by 0.55. Furthermore, as the current density decreases, the SnNi catalyst with saccharin has a slow decrease rate and higher stability than the SnNi catalyst without saccharin.
subject: Articles
  topic: section
subject: electrodeposition
  topic: keywords
subject: SnNi
  topic: keywords
subject: electrocatalyst
  topic: keywords
subject: ethanol electrooxidation
  topic: keywords
creator: Rinda Mulmeyda
creator: Abdul Ghofur Sidik
creator: Chika Shafa Maura
creator: Abdul Asywalul Fazri
rights: Copyright (c) 2024 Rinda Mulmeyda, Abdul Ghofur Sidik, Chika Shafa Maura, Abdul Asywalul Fazri https://creativecommons.org/licenses/by/4.0
date: 2024-10-31
publication date: 2024-10-31
starting page: 107
ending page: 115
doi: 10.56425/cma.v3i3.85

Electrodeposition of Thin Film Cu-Zn-Sn Alloy for Water Splitting Application
type: item
description: An energy transition to renewable energy sources is necessary due to the scarcity of fossil fuels and their detrimental effects on the environment. Water splitting process is one of the practical and effective way that does not occur spontaneously. This study investigates catalytic activity of Cu-Zn-Sn (CZT) photocatalyst in hydrogen evolution and oxygen evolution reaction. The CZT deposited with varied electrolyte’s pH of 6 and 9 on indium tin oxide substrate at the room temperature for 600 seconds. According to the X-ray diffraction patterns, there were Cu6Sn5, Cu5Zn8, and Sn metal phases with monoclinic, cubic, and cubic crystal systems. The scanning electron microscopy technique results of all CZT alloy sample showed a dense, non-uniform, and polycrystalline surface structure. The CZT alloys were found to have an average particle size of 0.35 μm. CZT alloys can produce a photocurrent density of 0.19 mA/cm² at a potential of 1.29 V vs RHE. the charge transfer resistance of CZT synthesized at pH 6 is lower (21.48 Ω) compared to pH 9 (28.36 Ω). The Tafel slope of HER for pH 9 CZT was -133 mV/dec, which was lower than that of pH 6 CZT (-88 mV/dec), indicating faster H2 production and corrosion resistance on pH 9 CZT.
subject: Articles
  topic: section
subject: electrodeposition
  topic: keywords
subject: CZT alloy
  topic: keywords
subject: water splitting
  topic: keywords
creator: Reinardo Ramawijaya Widakusuma
creator: Fathir Azzaki Iradata
creator: Mokhamad Ali Rizqi Maulana
creator: Ikhwan Nur Rahman
rights: Copyright (c) 2024 Reinardo Ramawijaya Widakusuma, Fathir Azzaki Iradata, Mokhamad Ali Rizqi Maulana, Ikhwan Nur Rahman https://creativecommons.org/licenses/by/4.0
date: 2024-10-31
publication date: 2024-10-31
starting page: 80
ending page: 89
doi: 10.56425/cma.v3i3.82

Additive-free Electrodeposition of SnCoNi Trimetallic Catalysts for Ethanol Electrooxidation
type: item
description: SnCoNi catalysts were synthesized via electrodeposition, with and without citric acid, to assess their ethanol electrooxidation performance. The additive-free catalyst exhibited superior properties, including lower charge transfer resistance and a smaller Tafel slope compared to the citric acid-modified catalyst. Chronoamperometry testing further revealed better electrochemical stability for the additive-free catalyst, with less current loss over time. Cyclic voltammetry confirmed the enhanced ethanol oxidation activity with a relatively high current density. The improved performance is attributed to better mass transport, active site exposure, and the synergistic effects of Sn, Co, and Ni in the additive-free catalyst, making it more efficient for ethanol electrooxidation. These findings suggest that the additive-free catalyst exhibits more favorable properties for ethanol electrooxidation compared to its citric acid-modified counterpart.
subject: Articles
  topic: section
subject: electrodeposition
  topic: keywords
subject: ethanol electrooxidation,
  topic: keywords
subject: electrocatalyst
  topic: keywords
creator: Qori'atun Ni'mah Salsabila
creator: Fabian Glorious Kenaya
creator: Muhammad Fathar Aulia
creator: Muhammad Athariq
rights: Copyright (c) 2024 Qori'atun Ni'mah Salsabila, Fabian Glorious Kenaya, Muhammad Fathar Aulia, Muhammad Athariq https://creativecommons.org/licenses/by/4.0
date: 2024-10-31
publication date: 2024-10-31
starting page: 90
ending page: 97
doi: 10.56425/cma.v3i3.84

Synthesis of Copper(I) Oxide Thin Film Through Potentiostatic Electrodeposition as an Antioxidant Film
type: item
description: Research on metal-based nanoparticles, such as silver, gold, and copper(I) oxide (Cu2O), has drawn considerable attention due to their potential applications in catalysis, antioxidants, antimicrobials, and anticancer fields. In this study, we successfully deposited Cu2O antioxidant films on indium tin oxide substrates through potentiostatic electrodeposition. The X-ray diffraction characterization revealed distinct peaks at 2θ value of 36.32°, 42.21°, and 61.30°, indicating the crystal structure of Cu2O thin film. The scanning electron microscopy image showed the three-sided pyramid morphology of Cu2O particles with average size of 316.18 nm. The energy dispersive X-ray spectrum confirmed the purity of the thin film, which is composed only of Cu and O elements without any impurities. The photoelectrochemical showed that the deposited Cu2O has a maximum photocurrent density of 8.37 mA/cm² under visible light irradiation and 1.40 mA/cm² without irradiation. In addition, this study also found that the highest inhibition values of DPPH (2,2-diphenyl-1-picrylhydrazyl) radicals were observed when ascorbic acid was added.
subject: Articles
  topic: section
subject: antioxidant
  topic: keywords
subject: ascorbic acid
  topic: keywords
subject: Cu2O nanofilm
  topic: keywords
subject: electrodeposition
  topic: keywords
creator: Muhammad Adya Raihan
creator: Shirly Harissyah Alfiani
creator: Sabrina Putri Chaerani
creator: Rachmaniah Nurul Imani
creator: Alsifa Andita Putri
rights: Copyright (c) 2024 Muhammad Adya Raihan, Shirly Harissyah Alfiani, Sabrina Putri Chaerani, Rachmaniah Nurul Imani, Alsifa Andita Putri https://creativecommons.org/licenses/by/4.0
date: 2024-10-31
publication date: 2024-10-31
starting page: 98
ending page: 106
doi: 10.56425/cma.v3i3.83

Decorating Cu2O with Copper Metal (Cu) through Facile Electrochemical Deposition for Methylene Blue Degradation
type: item
description: A cuprous oxide (Cu2O) thin film was decorated with copper metal (Cu) using a simple electrochemical deposition method on a substrate of indium tin oxide at a potential of -0.3 V vs. Ag/AgCl and a temperature of 60 °C. This study aimed to investigate the role of Cu as a co-catalyst. The structure, phase, and morphology of Cu2O/Cu were characterized by X-ray diffraction, scanning electron microscopy, and energy-dispersive X-ray spectroscopy, respectively. The electrocatalytic performance of Cu2O/Cu was recorded using linear sweep voltammetry and electrochemical impedance spectroscopy techniques. The X-ray diffraction and scanning electron micrograph show that Cu was successfully deposited covering Cu2O. The current density of Cu2O/Cu increased by 2.70 mA/cm2 confirming the lower charge current resistance of 2.48 kΩ. The Cu-decorated Cu2O demonstrated an improved photocatalytic activity, as shown by increased MB degradation from 46.33% to 50.87%. It was believed from characterizations that Cu deposition leads to more dense carriers and charge transfer, hence higher photocatalytic activity towards MB degradation than bare Cu2O thin film.
subject: Articles
  topic: section
subject: photocatalyst
  topic: keywords
subject: photodegradation
  topic: keywords
subject: non-noble metal
  topic: keywords
subject: co-catalyst
  topic: keywords
subject: Cu2O
  topic: keywords
creator: Shyla Noureen Zahra
creator: Firgie Wulandari
creator: Muhammad Raihan Rauf
creator: Ayuningsih Arum
rights: Copyright (c) 2024 Shyla Noureen Zahra, Firgie Wulandari, Muhammad Raihan Rauf, Ayuningsih Arum https://creativecommons.org/licenses/by/4.0
date: 2024-10-31
publication date: 2024-10-31
starting page: 71
ending page: 79
doi: 10.56425/cma.v3i3.81

Synthesis Dithizone-Immobilized In Polivinyl Chloride Membranes For Copper Detection in Water
type: item
description: A simple, cost-effective, and environmentally friendly analytical method is needed to determine Cu (II) levels in water. Many methods have been developed by immobilizing dithizone in a polyvinyl chloride (PVC) matrix with dioctyl phthalate (DOP) as a plasticizer in a tetrahydrofuran (THF) solvent. However, the optimal composition of PVC, DOP, and THF has not been determined. The purposes of this study were to determine the optimal composition of dithizone, PVC, and DOP for the sensor membranes, evaluate the performance of the chemical sensors in detecting Cu (II) ions, and measure the copper content in conventional drinking water. The research began with the fabrication of sensor membranes, followed by absorbance testing, and concluded with method validation through characterization. Adsorption of Cu (II) caused the membrane colour to change from yellow to reddish orange, with maximum absorbance observed at 427 nm. The sensor membrane exhibited the best response to Cu (II) ions at pH 2.8. A linear calibration curve for Cu (II) was obtained in the concentration range of 0-0.6 ppm, with an R² value of 0.9924. The limit of detection was 1.9881 x 10⁻³ mg L⁻¹, and the limit of quantification was 6.0245 x 10⁻³ mg L⁻¹. The molar absorptivity was 9.4831 x 10⁴ L mol⁻¹ cm⁻¹. The proposed sensor membrane was used to measure Cu (II) in drinking water employing the internal standard addition method, with observed recoveries ranging from 98.63% to 100.29%. The copper levels in the drinking water samples tested in this study did not exceed the drinking water quality standards set by PERMENKES RI number 492/PER/IV/2010.
subject: Articles
  topic: section
subject: sensor membrane
  topic: keywords
subject: dithizone
  topic: keywords
subject: validation method
  topic: keywords
subject: polyvinyl chloride.
  topic: keywords
creator: Yussi Pratiwi
creator: Yogi Febrian
creator: Angelina Klaudia
rights: Copyright (c) 2024 Yussi Pratiwi, Yogi Febrian, Angelina Klaudia https://creativecommons.org/licenses/by/4.0
date: 2024-06-30
publication date: 2024-06-30
starting page: 56
ending page: 63
doi: 10.56425/cma.v3i2.80

Square Wave Pulse Deposition of Gold Nanoparticles for Ethanol EOR Performance and Its Electrochemical Properties Investigation
type: item
description: In this study, gold nanoparticles (Au NPs) were successfully synthesized using square wave pulse deposition. The synthesis process involved applying a lower potential of -0.1 V and an upper potential of 0 V for 25 minutes. Characterization of the synthesized Au NPs was conducted using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray (EDX) spectroscopy, electrochemical impedance spectroscopy (EIS), and cyclic voltammetry (CV). The XRD analysis confirmed the formation of the Au phase on the FTO substrate. The SEM images revealed a nanopyramid-like morphology, with an average particle size ranging from 20 to 200 nm. The EIS measurements indicated low resistance values for the Au NPs. During the CV test for ethanol electrooxidation, a stable electric current of 4.28 mA/cm² was achieved, demonstrating good stability in the electrochemical process.
subject: Articles
  topic: section
subject: gold nanoparticle
  topic: keywords
subject: electrodeposition
  topic: keywords
subject: ethanol electrooxidation.
  topic: keywords
creator: Amir Mahmud
creator: Bimo Tri Goutomo
rights: Copyright (c) 2024 Amir Mahmud, Bimo Tri Goutomo https://creativecommons.org/licenses/by/4.0
date: 2024-06-30
publication date: 2024-06-30
starting page: 45
ending page: 49
doi: 10.56425/cma.v3i2.75

Antioxidant Activity of AuPt Nanoparticle with Square-Wave Pulse Deposition Method
type: item
description: Gold nanoparticles and platinum nanoparticles are considered to be effective antioxidants due to their ability in inhibiting free radicals. In this research, AuPt nanoparticles were synthesized using a square wave pulse deposition method by varying the lower potential (EL). The XRD results stated that AuPt nanoparticles had formed on the FTO substrate. The shape of AuPt nanoparticles is an irregular sphere in SEM-EDX characterization. EDX characterization also concluded that AuPt nanoparticles had formed on the FTO substrate. Antioxidant testing using the DPPH test resulted the largest inhibition value for AuPt NPs, with a lower potential of -0.6 V and the inhibition activity of 77.17%.
subject: Articles
  topic: section
subject: antioxidant activity
  topic: keywords
subject: electrodeposition
  topic: keywords
subject: AuPt nanoparticles.
  topic: keywords
creator: Devi Indrawati Syafei
rights: Copyright (c) 2024 Devi Indrawati Syafei https://creativecommons.org/licenses/by/4.0
date: 2024-06-30
publication date: 2024-06-30
starting page: 39
ending page: 44
doi: 10.56425/cma.v3i2.79